4.7 Article

A borane-bithiophene-BODIPY triad: intriguing tricolor emission and selective fluorescence response towards fluoride ions

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 76, Pages 8558-8560

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc42979b

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Funding

  1. Department of Science and Technology (DST), New Delhi
  2. CSIR, New Delhi
  3. IISc

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The structure and photophysical properties of a new triad (borane-bithiophene-BODIPY) 1 have been investigated. Triad 1 exhibits unprecedented tricolour emission when excited at the borane centred high energy absorption band and also acts as a selective fluorescent and colorimetric sensor for fluoride ions with ratiometric response. The experimental results are supported by computational studies.

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