Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 6, Pages 633-635Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37651b
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- Karlsruhe Institute of Technology (KIT)
- German Research Council (DFG)
- Ministry of Science and Arts of the State of Baden-Wurttemberg
- Karlsruhe Nano Micro Facility (KNMF), a Helmholtz Research Infrastructure at the KIT
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An efficient method for polymer surface patterning via Diels-Alder trapping of photo-generated thioaldehydes is presented. It is demonstrated that thioaldehyde end-groups generated by photolysis of phenacyl sulfides can be quantitatively trapped with various dienes. Poly(ethylene glycol) is immobilized on a surface in a spatially controlled fashion via irradiation through a shadow mask.
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