Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 77, Pages 8662-8664Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc44899a
Keywords
-
Categories
Funding
- University of Cyprus (Medium Sized Grants)
- Cyprus Research Promotion Foundation [YGEIA/BIOS/0308(BIE)/13, NEKYP/0308/02]
- Israel Science Foundation
- CFI
- ORF
- EPSRC [EP/K017322/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K017322/1] Funding Source: researchfish
Ask authors/readers for more resources
7-(Fur-2-yl) benzotriazinyl 1 is the first example of a hydrazyl radical dimer with a thermally accessible triplet state. The triplet exciton (vertical bar D vertical bar = 0.018 cm(-1), vertical bar E vertical bar = 0.001 cm(-1)) was observed by solid-state VT-EPR spectroscopy between 5 and 140 K. VT crystallography, DFT calculations and magnetic susceptibility studies reveal a strong temperature dependence of the intra-dimer exchange interaction with J/k similar to -254 + 0.0007T(2).
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
