4.7 Article

Dimerization of cyclopropenes to bifurans using tandem metal relay catalysis

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 80, Pages 9167-9169

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc44762f

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Funding

  1. Natural Science Foundation of China and Shandong Province [21102085, BS2012YY006]
  2. Ministry of Education of China [20110131120049]

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An efficient synthesis of bifurans via dimerization of cyclopropenes has been successfully developed using a copper-promoted cycloisomerization and palladium-catalyzed dimerization cascade. These novel bifuran structures possess interesting optoelectronic properties.

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