4.7 Article

A unique magnesium-based 3D MOF with nanoscale cages and temperature dependent selective gas sorption properties

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 17, Pages 1753-1755

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc38730e

Keywords

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Funding

  1. 973 Program of China [2012CB821705]
  2. NSFC [20831005, 21121061, 91127002]
  3. NSF of Guangdong Province [S2012030006240]

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A porous Mg-based 3D metal-organic framework with unique nanoscale cages and two-fold interpenetrating pcu nets has been synthesized and characterized. It shows gas-uptake capacities for N-2, H-2, O-2 and CO2 at low temperatures and selective adsorption of CO2 over O-2 and N-2 at room temperature.

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