4.7 Article

A two-dimensional zeolitic imidazolate framework with a cushion-shaped cavity for CO2 adsorption

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 82, Pages 9500-9502

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc44342f

Keywords

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Funding

  1. ARC [FT100100192]
  2. Monash University
  3. NKSTPC [2011BAE07B05]
  4. NNSFC [20990222, 21106061, 21171093]
  5. NSF of Jiangsu Province [BK2010549, BK2009021]
  6. Swiss National Science Foundation

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A new two-dimensional zeolitic imidazolate framework (named as ZIF-L) was synthesized in zinc salt and 2-methylimidazole (Hmim) aqueous solution at room temperature. ZIF-L (Zn(mim)(2)center dot(Hmim)(1/2)center dot(H2O)(3/2) or C10H16N5O3/2Zn) has unique cushion-shaped cavities and leaf-like crystalmorphology, and exhibits excellent CO2 adsorption properties.

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