4.7 Article

Selective aerobic oxidation of amines to imines by TiO2 photocatalysis in water

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 44, Pages 5034-5036

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc41407h

Keywords

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Funding

  1. 973 project [2010CB933503, 2013CB632405]
  2. NSFC [21137004, 21273245, 21277147]
  3. CAS

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Selective oxidation of benzylic amines to imines with atmospheric O-2 is achieved in water on TiO2 under UV irradiation. The afforded imine could be easily separated and TiO2 can be recycled by filtration. To scale up, gram-scale imine products can be obtained.

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