4.7 Article

A redox-active luminescent ytterbium based single molecule magnet

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 6, Pages 615-617

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37635k

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Funding

  1. Region Bretagne
  2. Rennes Metropole
  3. CNRS
  4. Universite de Rennes 1
  5. FEDER

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A redox active dinuclear complex [Yb(tta)(2)(L-1)(L-2)](2)center dot 1.4(CH2Cl2) displays single molecule magnet behaviour with M-J = +/- 7/2 ground state. The anisotropic barrier Delta is evaluated by the three dc data fit, ac analysis and emission spectrum demonstrating the correlation between magnetic and optical properties.

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