4.7 Article

Colorimetric and fluorescent pH and Cu2+ probes induced by photoisomerization of a maleonitrile-based Salen ligand

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 100, Pages 11791-11793

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47137c

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Funding

  1. National Natural Science Foundation of China [21172160, 21372169]

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Both photo-induced cis-trans-isomers of a maleonitrile-based Salen ligand can be used as pH probes covering a broad pH range through three different mechanisms but upon undergoing the formation of a stable complex and Cu2+-promoted hydrolysis, respectively, they exhibit totally different responses and mechanisms for sensing Cu2+.

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