Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 65, Pages 7246-7248Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43133a
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Funding
- Spanish MICINN [CTQ2010-18901/BQU]
- JCyL [VA281A11-2, VA373A11-2]
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AuClL1/PdCl2L22 cocatalyzed coupling of Ar1X and (ArSnBu3)-Sn-2 is feasible for bulky Ar-1, provided that at least one ligand on Pd is not strongly coordinating. This can be achieved in situ by Au/Pd ligand exchange if L-1 is weakly coordinating. When the exchange is slow, independent preparation of appropriate catalysts is recommended.
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