Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 100, Pages 11758-11760Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47551d
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Funding
- Singapore National Research Foundation [NRF-RF2008-10]
- Nanyang Technological University
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An asymmetric Heck reaction allows desymmetrization of substituted cyclic olefins in high dr and ee. A bisphosphine oxide is uniquely stereoselective for this purpose. Desymmetrization of bicyclic olefins via hydroarylation can also be realized in high ee.
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