4.7 Article

Lanthanide-polyphosphonate coordination polymers combining catalytic and photoluminescence properties

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 57, Pages 6400-6402

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc42632g

Keywords

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Funding

  1. FCT [PTDC/QUI-QUI/098098/2008 (FCOMP-01-0124-FEDER-010785), SFRH/BD/66371/2009, SFRH/BD/84495/2012, SFRH/BD/84231/2012, SFRH/BPD/63736/2009]
  2. Fundação para a Ciência e a Tecnologia [PTDC/QUI-QUI/098098/2008, SFRH/BD/84495/2012] Funding Source: FCT

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A rapid, mild and high-yield microwave synthesis of 1D isotypical [Ln(H(4)bmt)(H(5)bmt)(H2O)(2)]center dot 3H(2)O coordination polymers is presented. The La3+-based material is highly active as a heterogeneous catalyst in the methanolysis of styrene oxide at nearly room temperature. Eu3+- and Tb3+-doped materials are very effective UV-to-visible light converters.

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