4.7 Article

Intramolecular reorganization energy in zinc phthalocyanine and its fluorinated derivatives: a joint experimental and theoretical study

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 54, Pages 6069-6071

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc42003e

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Funding

  1. CNPq
  2. CAPES
  3. FAP-DF (Fundacaco de Apoio a Pesquisa do Distrito Federal)
  4. National Science Foundation under the MRSEC Program [DMR-0819885]

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We report a high-resolution gas-phase UPS spectrum of zinc phthalocyanine (ZnPc) together with a detailed analysis of the vibronic structure of the first ionization band, showing that ZnPc presents the lowest value of the intramolecular reorganization energy experimentally reported for a molecular organic semiconductor.

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