Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 53, Pages 5990-5992Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43016b
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Funding
- U.S. National Science Foundation [CHE-1057659]
- Republic of Turkey
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1057659] Funding Source: National Science Foundation
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(N-heterocyclic carbene)gold(I) alkynyls and organic azides have undergone cycloadditions in water-t-butanol mixtures with copper metal as the pre-catalyst to give new gold(I) triazolyls in high purity. Substrate tolerability was outlined for organoazides bearing a range of functional groups, and branching alpha to the azide moiety. All products are validated by combustion analysis or high-resolution mass spectrometry; two are also confirmed crystallographically.
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