Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 56, Pages 6271-6273Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43267j
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Funding
- Canada Foundation for Innovation (CFI)
- Ontario Ministry of Economic Development and Innovation (MEDI)
- U. Guelph
- ANR [NT09_469563]
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The first coordination polymer of a bridging radical 1,2,3,5-dithiadiazolyl ligand is reported. Upon coordination with the La(hfac)(3) fragment, the paramagnetic 4-(benzoxazol-2'-yl)-1,2,3,5-dithiadiazolyl (boaDTDA) ligand forms a one-dimensional (1D) alternating -[La(hfac)(3)boaDTDA](n)- polymer exhibiting ferromagnetic (FM) coupling between the radicals, mediated through the diamagnetic La-III ion (hfac = 1,1,1,5,5,5-hexafluoroacetylacetonato).
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