4.7 Article

Metal ion directed metal-organic rotaxane frameworks with intrinsic features of self-penetration and interpenetration

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 76, Pages 8555-8557

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43990a

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Funding

  1. NSFC of China [21001022, 21171033, 21131001, 21222105, 21071124, 21173189]
  2. PhD Station Foundation of Ministry of Education [20100043110003]
  3. Foundation for Author of National Excellent Doctoral Dissertation of P. R. China (FANEDD) [201022]
  4. Science and Technology Development Planning of Jilin Province [201001169, 20111803]

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Three novel self-catenated 4-connected uninodal (6(5).8)-mok metal-organic rotaxane frameworks (MORFs) containing cucurbit[6]uril were constructed from the in situ trans/cis-configuration (1:1) of rotaxanes by taking advantage of a d(10) metal ion directed synthesis. It was revealed that the effect of hydrogen bonds and pi-pi stacking interactions play significant roles in the self-assembly process.

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