Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 71, Pages 7806-7808Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc44276d
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Funding
- Council of Scientific and Industrial Research, New Delhi, India (CSIR) [09/096(0586)/2009-EMR-I]
- Spanish Ministerio de Economia y Competitividad [CTQ2011-26507, CSD2010-00065]
- Generalitat Valenciana (Prometeo Program)
- Generalitat Valenciana (ISIC Program)
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An easy reversible switching of the electronic ground state in a pentacoordinated copper(II) complex is reported for the first time. The simple protonation of a carboxylic group in a Cu(II) complex with a {d(x2-y2)}(1) electronic configuration leads to a flip of the ground electronic configuration from {d(x2-y2)}(1) to {d(z2)}(1) in the metal ion.
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