Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 51, Pages 5718-5720Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc00219e
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Funding
- 973 Program [2011CBA00505]
- National Key Technology RD Program [2012BAE06B08]
- NSF of China [21003126, 21203200]
- Key Project from the CAS [KJCX2.YW.M10]
- NSF of Fujian province [2012J05032]
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A Pd/alpha-Al2O3 nanocatalyst with ultra-low Pd loading exhibits high activity and stability for CO oxidative coupling to dimethyl oxalate, which was prepared by a Cu2+-assisted in situ reduction method at room temperature. The small size and high dispersion of Pd nanoparticles facilitated by Cu2+ ions are responsible for the excellent catalytic activity.
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