Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 21, Pages 2121-2123Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc38897b
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Synthesis under hydrofluorothermal conditions produces new iron, manganese and vanadium fluorosulfates; these include the isomorphous (Na3MF2)-F-III(SO4)(2), M = V, Mn, Fe, with a sheet-like structure formed of linked (MF2O4)-F-III and SO4 polyhedra separated by sodium ions which may be extracted electrochemically at potentials of >3.5 V.
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