Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 46, Pages 5256-5258Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc41176a
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Funding
- Grants-in-Aid for Scientific Research [24108742] Funding Source: KAKEN
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By utilizing different coordination properties of a lanthanide ion and a transition metal ion, a heterometallo-supramolecular polymer with Eu(III) and Fe(II) ions introduced alternately (polyEuFe) was precisely prepared via stepwise complexation of the metal ions to a new unsymmetrical ligand with both a dicarboxylate-substituted terpyridine and an unsubstituted terpyridine. The polymer showed unique, reversible on-off'' switching of the Eu(III) luminescence by electrochemical redox of the Fe ions in the solid-state.
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