4.7 Article

Gold-catalysed tuning of reactivity in allenes: 9-endo hydroarylation versus formal 5-exo hydroalkylation

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 13, Pages 1282-1284

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37872h

Keywords

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Funding

  1. MICINN [CTQ2009-09318, CTQ2010-20714-C02-01, CSD2007-00006]
  2. CAM [S2009/PPQ-1752, S2009/PPQ-1634]
  3. Comunidad Autonoma de Madrid
  4. Fondo Social Europeo

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The divergent gold-catalysed reactivity (C-sp2-H versus C-sp3-H) of aryloxy-tethered allenes has been uncovered.

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