Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 44, Pages 5004-5006Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc40987b
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Funding
- French National Research Agency (ANR, Labex program ARCANE) [11-LABX-003]
- Life Science Division of the CEA (BioHydrogen program)
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A combined electrochemical and theoretical study suggests that hydrogen evolution from weak acids catalyzed by a structural mimic of the active site of NiFe hydrogenases [Ni(xbsms)Ru(C6Me6)Cl](+) proceeds through proton-coupled electron transfer steps.
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