Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 74, Pages 8220-8222Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43898h
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Funding
- Applied Basic Research Projects (Industry) of Suzhou City [SYG201253]
- NSFC [50903081, 21171156]
- 973 Program [2012CB932502]
- CPSFP [20100480683, T201250545]
- NSFJSP [BK2008579]
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The ligand tppda has been designed and synthesized as molecular leverage for helicity control when reacted with Cd2+ ions. The guests MeOH or DMF preferentially stabilize the P-helical isomer, while the guest H2O causes a helix inversion to give the M-helical isomer as the major isomer without any chiral auxiliary.
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