4.7 Article

High-performance low-bandgap conjugated polymers bearing diethynylanthracene units for thin-film transistors

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 37, Pages 3896-3898

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc40397a

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Funding

  1. National Research Foundation of Korea [NRF2012R1A2A1A01008797, 20110026418]
  2. Key Research Institute Program through the NRF
  3. Ministry of Education, Science and Technology [NRF20120005860]

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Novel donor-acceptor pi-conjugated copolymers, P(DPP-BDT) and P(DPP-ANT), were synthesized in 87-89% yield. Thin-film transistors (TFTs) made from the thermally annealed film of P(DPP-ANT) exhibited much better performance (e.g., mu(max) = 1.90 cm(2) V-1 s(-1), I-on/off approximate to 10(6)) than those made from the thermally annealed film of P(DPP-BDT).

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