4.7 Article

Relaxations in heterolanthanide dinuclear single-molecule magnets

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 2, Pages 158-160

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37036k

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Funding

  1. NSFC [91122032, 90922009, 21121061]
  2. 973 Project [2012CB821704]

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A heterospin dinuclear complex [Dy0.87Yb1.13(H(2)cht)(2)Cl-4(H2O)(MeCN)]center dot MeCN shows shifts of the relaxation barriers with respect to the barriers observed in homospin Dy-2 and Yb-2 isostructural complexes. The origin of slow relaxation in the latter two compounds was elucidated by ab initio calculations.

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