Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 9, Pages 889-891Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc38088a
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Funding
- National Key Basic Research Program of China [2013CB933402, 2012CB224801]
- Natural Science Foundation of China
- Beijing Municipal Commission of Education
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A hexakis[2,3,9,10,16,17,23,24-octa(butyloxy)phthalocyaninato] samarium(III)-cadmium(II) sextuple-decker complex (Pc*)Sm(Pc*)-Cd(Pc*)Cd(Pc*)Cd(Pc*)Sm(Pc*) (1) with six phthalocyanine ligands bridged by two samarium(III) and three cadmium(II) ions, representing the largest stacked tetrapyrrole metal molecule in the sandwich series in terms of the tetrapyrrole-deck number, has been synthesized and characterized spectroscopically and electrochemically. Investigation of the nonlinear optical properties reveals the excellent optical limiting property of this compound.
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