Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 39, Pages 4169-4171Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37193f
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Funding
- American Chemical society Petroleum Research Fund (PRF) [50460-DNI3]
- Purdue University
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Reduction of Cp*2UI(THF) with KC8 in the presence of a pyridine-(diimine) ligand (PDI) results in the formation of Cp*U(PDI)(THF), which features a triply reduced PDI ligand. This species performs four electron cleavage of azobenzene to generate the uranium bis(imido), Cp*(PDI)U(NPh)(2).
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