4.7 Article

Aerobic oxidative N-dealkylation of tertiary amines in aqueous solution catalyzed by rhodium porphyrins

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 39, Pages 4214-4216

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37263k

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Funding

  1. National Science Foundation of China [20801002, 21171012]

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Aerobic oxidative N-dealkylation of a variety of aliphatic tertiary amines and anilines catalyzed by rhodium(III) tetra (p-sulfonatophenyl) porphyrin ((TSPP)Rh-III) is achieved in aqueous solution using dioxygen as the sole oxidant.

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