4.7 Article

Dual emissive borane-BODIPY dyads: molecular conformation control over electronic properties and fluorescence response towards fluoride ions

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 10, Pages 993-995

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc38352g

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Funding

  1. Department of Science and Technology (DST), New Delhi
  2. CSIR, New Delhi
  3. ISRO-IISc Space Technology Cell
  4. IISc for SRF
  5. CSIR

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Facile synthesis of two new dimesitylboryl appended BODIPYs is reported. The two dyads have similar fluorescent chromophores but differ in their molecular conformations. They exhibit dual fluorescence, intramolecular energy transfer between boryl and BODIPY chromophores and different fluorescence responses (emission enhancement and quenching) upon fluoride binding.

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