Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 29, Pages 2992-2994Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc40819a
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Funding
- U.S. Department of Energy through BES [DE-FG02-08ER46522]
- DOE Office of Energy Efficiency and Renewable Energy, DOE ARPA-E
- Stanford Global Climate and Energy Project
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We show that the MOF NU-111 exhibits equally high volumetric and gravimetric methane uptake values, both within approximate to 75% of the DOE targets at 300 K. Upon reducing the temperature to 270 K, the uptake increases to 0.5 g g(-1) and 284 cc(STP) per cc at 65 bar. Adsorption of CO2 and H-2 is also reported. Simulated isotherms are in excellent agreement with those obtained from experiments.
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