4.7 Article

Synthesis and post-synthetic modification of MIL-101(Cr)-NH2 via a tandem diazotisation process

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 99, Pages 12053-12055

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36344e

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Funding

  1. EPSRC [EP/H046305/1]
  2. Engineering and Physical Sciences Research Council [EP/H046305/1] Funding Source: researchfish

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The functionalised metal-organic framework MIL-101(Cr)-NH2, containing 2-aminobenzene-1,4-dicarboxylate as the linker, has been synthesised. A new tandem post-synthetic modification strategy involving diazotisation as the first step has been developed and used to introduce halo-and azo dye-functional groups into the pores.

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