4.7 Article

Monofunctionalised cucurbit[6]uril synthesis using imidazolium host-guest complexation

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 25, Pages 3070-3072

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc17433b

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Funding

  1. Walters-Kundert foundation
  2. ERC
  3. Raymond & Helen Kwok Research Scholarship
  4. Herchel Smith Fund
  5. Engineering and Physical Sciences Research Council [EP/F035535/1] Funding Source: researchfish
  6. EPSRC [EP/F035535/1] Funding Source: UKRI

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Monohydroxylated cucurbit[6]uril was prepared for the first time through the controlled oxidation of CB[6] in the presence of a tailor-made bisimidazolium guest, as verified by H-1 NMR, ESI-MS and X-ray crystallography. Further chemical modification of monohydroxylated CB[6] was also readily achieved.

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