4.7 Article

Sodium zinc hexacyanoferrate with a well-defined open framework as a positive electrode for sodium ion batteries

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 67, Pages 8416-8418

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33771a

Keywords

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Funding

  1. National Research Foundation of Korea Grant
  2. Korean Government (MEST) [NRF-2009-0094219, NRF-2010-0029031, NRF-2012-R1A2A1A01011970]
  3. WCU program [R-31-10055-0]
  4. Cooperative Research Project [B551179-12-02-00]

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A modified Prussian blue analogue, Na2Zn3[Fe(CN)(6)](2)center dot xH(2)O, was investigated as a positive electrode material. Utilizing a well-defined channel structure, the compound exhibits a clear electrochemical activity at around 3.5 V vs. Na/Na+ with a reversible capacity of 56.4 mA h g(-1) and good cycle life.

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