Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 70, Pages 8823-8825Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33583b
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- U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [DE-SC0002576]
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The first microcrystalline borazine-linked polymer, BLP-2(H), has been synthesized. BLP-2(H) crystallizes into 2D sheets that stack in an eclipsed AA fashion, has high thermal stability (similar to 420 degrees C) and high porosity (SA(BET) = 1178 m(2) g(-1)) and it can store up to 2.4 wt% of hydrogen at 77 K and 15 bar with isosteric heat of adsorption of 6.8 kJ mol(-1).
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