4.7 Article

New highly soluble dimedone-derived iodonium ylides: preparation, X-ray structure, and reaction with carbodiimide leading to oxazole derivatives

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 81, Pages 10108-10110

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35708a

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Funding

  1. NSF [CHE-1009038, MRI CHE-0922366]
  2. Research and Innovation Plan for Graduate Students of Jiangsu Higher Education Institutions [CXZZ11_0266]
  3. Direct For Mathematical & Physical Scien
  4. Division Of Chemistry [1009038] Funding Source: National Science Foundation

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Highly soluble dimedone-derived o-alkoxyphenyliodonium ylides have been prepared and characterized by single crystal X-ray diffraction. These new iodonium ylides are useful reagents for the preparation of oxazole derivatives by reaction with carbodiimides.

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