4.7 Article

Approaching a stable, green twisted heteroacene through clean reaction'' strategy

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 48, Pages 5974-5976

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc32048g

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Funding

  1. Nanyang Technological University
  2. MOE [RG 18/09]
  3. NRF
  4. NTU, Singapore
  5. NSF while at UCLA

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A new, longest, stable, green twisted heteroacene 2-methyl-1,4,6,13-tetraphenyl-7:8,11:12-bisbenzo-anthro[g]isoquinolin-3(2H)-one (3) was synthesized by employing a clean reaction'' strategy based on thermally eliminating lactam bridges. Calculation shows that the HOMO-LUMO bandgap is in good agreement with experimental data.

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