4.7 Article

Slow magnetic relaxation in a pseudotetrahedral cobalt(II) complex with easy-plane anisotropy

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 33, Pages 3927-3929

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc16430b

Keywords

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Funding

  1. DoE/LBNL [403801]
  2. NSF [CHE-1111900, DMR-0804408, DMR-0654118]
  3. State of Florida
  4. Tyco Electronics
  5. Miller Institute for Basic Research
  6. Direct For Mathematical & Physical Scien
  7. Division Of Chemistry [1111900] Funding Source: National Science Foundation
  8. Division Of Materials Research
  9. Direct For Mathematical & Physical Scien [804408] Funding Source: National Science Foundation

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A pseudotetrahedral cobalt(II) complex with a positive axial zero-field splitting parameter of D = 12.7 cm(-1), as determined by high-field EPR spectroscopy, is shown to exhibit slow magnetic relaxation under an applied dc field.

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