Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 59, Pages 7362-7364Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33094f
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Funding
- Ministry of Science and Higher Education [N N204 142237, N N204 164336, N N204 527939]
- European Union through the Warsaw University of Technology Development Programme of ESF
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Two unique adducts of an oxozinc carboxylate cluster with H2O and THF were isolated and structurally characterized, [Zn-4(mu(4)-O)(O2CR)(6)(H2O)(THF)]center dot 2(THF) and [Zn-4(mu(4)-O)(O2CR')(6)-(THF)(3)] (where R = benzoate and R' = 9-antracenecarboxylate anion). The study shows that the zinc centers of the Zn4O core can easily form unique coordination environments without breaking of the Zn-O-carboxylate bonds.
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