4.7 Article

Pillar[5]arene-based polymeric architectures constructed by orthogonal supramolecular interactions

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 68, Pages 8529-8531

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33943a

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Funding

  1. National Natural Science Foundation of China [20932004, 21072093]
  2. National Basic Research Program of China [2011CB808600]
  3. Natural Science Foundation of Jiangsu [BK2011055, BK2011551]

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Ureidopyrimidinone functionalized pillar[5]arene (UPyP5) was synthesized and employed to complex with a bisparaquat derivative (G) to form supramolecular polymers at relatively high concentration. The orthogonal binding interactions including quadruple hydrogen bonding and host-guest interaction should play vital roles in the construction of this linear assembly.

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