4.7 Article

A supramolecularly templated catenane initiator and a controlled ring expansion strategy

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 99, Pages 12094-12096

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35588d

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Funding

  1. NSF EAGER [1247438]
  2. Direct For Mathematical & Physical Scien
  3. Division Of Chemistry [1247438] Funding Source: National Science Foundation

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We report the first synthesis of a catenated polymer via a ring-expansion strategy, which is based on a supramolecularly templated initiator. The high yielding synthesis and simple isolation method will enable the investigation and development of this unique polymer system for further applications.

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