4.7 Article

High CO2 uptake and selectivity by triptycene-derived benzimidazole-linked polymers

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 8, Pages 1141-1143

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc16986j

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Funding

  1. U.S. Department of Energy, Office of Basic Energy Sciences [DE-SC0002576]

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Successful incorporation of triptycene into benzimidazole-linked polymers leads to the highest CO2 uptake (5.12 mmol g(-1), 273 K and 1 bar) by porous organic polymers and results in high CO2/N-2 (63) and CO2/CH4 (8.4) selectivities.

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