4.7 Article

From Grignard's reagents to well-defined Mg nanostructures: distinctive electrochemical and solution reduction routes

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 42, Pages 5169-5171

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31405c

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Funding

  1. SBIR Grant from the Department of Defense

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Anisotropic Mg nanowires have been successfully prepared by electrocrystallization of Grignard's reagents thought to proceed via a modified faces, steps, and kinks (FSK) mechanism. Mg nanoparticles with roughly hexagonal shapes have also been obtained via chemical reduction of the same Grignard's reagents.

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