Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 47, Pages 5844-5846Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc32321d
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Funding
- NNSF of China [21001022, 21171033, 21131001]
- NGFR of China [2010CB635114]
- NCET in Chinese University [NCET-10-0282]
- PhD Station Foundation of Ministry of Education [20100043110003]
- FANEDD of P.R. China [201022]
- STDP of Jilin Province [201001169, 20100182]
- FRFCU [09ZDQD003, 10CXTD001]
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Bridging between silver clusters and polyoxoanion clusters, the first 1D assembly, [Ag-34((SBu)-Bu-t)(26)(W6O21)(CF3COO)](CF3COO)center dot Et3N center dot 20CH(3)OH (1), based on POM- templated silverthiolate nanoclusters featuring a [Ag-34((SBu)-Bu-t)(26)(CF3COO)](7+) shell and a [W6O21](6-) core is reported. This novel core-shell nanocluster possesses nanoscopic morphology, displays intense deep-blue emission in solution under ambient conditions and also shows special electrochemical properties.
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