Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 40, Pages 4827-4829Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31091k
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A novel iron-catalyzed transfer hydrogenation of alkynes to the corresponding alkenes applying formic acid as a hydrogen donor is reported. An in situ combination of Fe(BF4)(2)center dot 6H(2)O and tetraphos allows for highly selective hydrogenation of a broad range of aromatic and aliphatic alkynes tolerating different functional groups.
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