Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 67, Pages 8407-8409Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34246d
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Funding
- German Research Foundation [SPP 1362]
- Helmholtz Centre Berlin
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Zr and Hf based MOFs with enhanced pore accessibility for large molecules and good hydrothermal stability were obtained using a bent dithienothiophene dicarboxylate and Zr4+ or Hf4+ source. A modulator (benzoic acid) facilitates formation of an eight-connecting cluster leading to a new framework which adopts reo topology.
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