4.7 Article

A long-lived photo-induced metastable state of linkage isomerization accompanied with a spin transition

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 46, Pages 5715-5717

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31326j

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In addition to the generally observed LIESST phenomenon, polymorph D of trans-[Fe-II(abpt)(2)(NCS)(2)] exhibits a long-lived photo-induced metastable state through linkage isomerization accompanied with a spin crossover transition, which is stable up to 108 K.

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