4.7 Article

Hydrogenolysis of lignosulfonate into phenols over heterogeneous nickel catalysts

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 56, Pages 7019-7021

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31414b

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Funding

  1. National Natural Science Foundation of China [21073184]
  2. One Hundred Person Project of the Chinese Academy of Sciences

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We report a strategy for the catalytic conversion of lignosulfonate into phenols over heterogeneous nickel catalysts. Aryl-alkyl bonds (C-O-C) and hydroxyl groups (-OH) are hydrogenated to phenols and alkanes, respectively, without disturbing the arenes. The catalyst is based on a naturally abundant element, and is recyclable and reusable.

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