4.7 Article

Porphyrin based porous organic polymers: novel synthetic strategy and exceptionally high CO2 adsorption capacity

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 2, Pages 248-250

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14275e

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Funding

  1. Nano Mission Initiative of DST, New Delhi
  2. CSIR, New Delhi

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Iron containing porous organic polymers (Fe-POPs) have been synthesized by a facile one-pot bottom-up approach to porphyrin chemistry by an extended aromatic substitution reaction between pyrrole and aromatic dialdehydes in the presence of small amount of Fe(III). The Fe-POPs possess very high BET surface area, large micropores and showed excellent CO2 capture (similar to 19 wt%) at 273 K/1 bar.

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