Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 66, Pages 8249-8251Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33547f
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- Universite de Montreal
- Natural Science and Engineering Council of Canada (NSERC)
- Canada Research Chair Program
- Canada Foundation for Innovation
- NSERC
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A variety of polycycles can be synthesized via an intramolecular alkylation cyclization promoted by Ni(PPh3)(4) and NaHMDS. Mechanistic investigations support the catalytic nature of Ni-0 in the course of TEMPO scavenging experiments and its association with the substrate and NaHMDS to form an adduct by DOSY NMR.
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