Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 71, Pages 8898-8900Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34380k
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Funding
- University of South Florida
- NSF [CHE-0844602]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0844602] Funding Source: National Science Foundation
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The replacement of the pillar ligand, 4,4'-bipyridine, in the prototypal pillared MOF, MOF-508, with the custom-designed ligand, 4,4'-(2H-1,2,3-triazole-2,4-diyl) dipyridine, affords a porous metal-triazolate framework, MTAF-3, which demonstrates remarkable enhancement of CO2 uptake capacity by a factor of similar to 3 compared to the parent MOF-508.
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